Abstrait

Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers, acetals and ketals with N,N’-dibenzyl-1,4-diazoniabicyclo [2.2.2] octane peroxodisulfate under non-aqueous conditions

Mohammad Alikarami, Zahra Abbasi


An efficient and convenient conversion of trimethylsilyl (TMS) and tetrahydropyranyl (THP) ethers, acetals and ketals to the corresponding carbonyl compoundswith N,NÂ’-dibenzyl-1,4-diazoniabicyclo [2.2.2] octane peroxodisulfate (DBDABCOPDS) under non-aqueous conditions is described.


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